Hi aleon,
Welcome to 5 Star.
Well not sure I have the whole picture BUT typically large corporations would not be "affiliates" they would be "merchants or advertisers." (Affiliates promote other people's products.) Not sure of your concept but doubt large corps would want to promote your program for a small commission.
Are you doing something similar to Upromise? If you can tell us a little more we can give you better info and ideas.
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