my advice: Join a few networks see what you like. Make sure you call and speak with a sales manager, a affiliate manager, and even ask if you can speak with the founder or CEO - that may be to much to ask but you will learn a lot about the company and how good the customer service is.
Before i started a network I was an web site owner, and affiliate marketer. I joined like 10 networks and then found a few i liked. I tried to stick with companies that had in-house tech, had good customer support, and unique offers. I really like the following companies and still work with them.
Advaliant
Shareasale
and of course i love Motive! But i guess i'm biased on that one.
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