Hi Wheeler,
Welcome to 5 Star!
Sounds like you are looking for pay per lead type programs as opposed to pay per sale? The good ones depend somewhat on your site content and the markets you want to pursue and have targeted traffic for. That's one thing with CPA thats pretty important is targeted traffic, unless you run very general consumer offers.
Some of the highest paying and converting CPA offers are financial. Mortgage, insurance, etc. 5 Star has NetQuote and ProspectZone that are independent and not on networks.
http://www.5staraffiliateprograms.co...insurance.html
http://www.5staraffiliateprograms.co...ffiliates.html
Let me know if those look like a good fit.